Spin–orbit autoionization and intensities in the double‐resonant delayed pulsed‐ field threshold photoionization of HCl
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چکیده
Articles you may be interested in Double-resonance spectroscopy of autoionizing states of ammonia Photoselection and the structure of highly excited states: Rotationally resolved spin–orbit autoionization spectrum of HCl State-selected delayed pulsed-field threshold photoionization spectra of HCI and DCI are recorded in double-resonant transitions through the F lA, E lI+, and g 3I-states of the 4P7T Rydberg configuration. Comparison of observed rotational line strengths with calculated spectra, as well as with available time-of-flight photoelectron spectra, provides useful insight on the influence of spin-orbit and rotational autoionization on delayed pulsed-field threshold photoionization of HCI. Spin-orbit and rotational autoionization are seen to dramatically reduce the ion rotational intensity associated with the upper spin-orbit level of the ion.
منابع مشابه
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تاریخ انتشار 2015